Some games need vr being activated in their ingame options. Someneed you to launch them vua Steam launcher and then choosing betwenn various 2D and VR options. Some may still need a command line added in steam properties.
This is Windows Mixed Reality mode, technically. Games have best chances to run properly if launched not via shortcut but from within the vurtual steam home that automatically launches after hardware got connected. Else the controllers might get messed up.
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