I dont think this is a Windows 10 problem. I had the same problem with SC on Windows XP. It just hung. You should download and try a No-CD patch / crack. I think it might already come with one in the ISO file. It will replace the icon you use to start the game with another icon, then you double-click on that new icon, and then the game should run. Thats what I did, and then SC worked on my PC.
In my opinion, however, Windows XP is still the best OS for all games that do not require DirectX10 or higher. SC requires only DirectX8.