The page file does not defrag on shut down nor does it go away.
However, without using another program you can defrag the drive if you have more than one partition.
Just create a page file on the other partition and delete the page file you want to defrag and reboot. Then defrag the partition that the old page file was on. Saving some time you could just let it stand that way untill you were ready to defrag the page file again then repeat the process the other way.
Or you could get a program that does it for you.
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