I have the 8800 GTS, and I usually leave all the settings in the nvidia control panel alone and let the computer manage them...
I run SH4 at 1152x864, max out 3d damage, characters detail, particle density.
Terrain objects about 7/8 across, LOD size 3/4, gamma about 1/2.
Have got ticked, Light shafts, Enviromental effects, and everything on the right hand side.
Everything runs great and looks terrific in my game...
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