Get a tool like TweakXP or something like it that let's you reorganise your RAM. It rearranges what's loaded into RAM and drops out some of the extraneous crap that Windoze leaves lying about cluttering up your gaming experience.
Also as long as you are not going online, kill your virus checker and firewall software and anything else that you can kill that's is open in the system tray. If you do this before running your memory organiser, you can save heaps of RAM which is one resource that SHIII is a real hog on.
Don't discount running a regular defrage either as this can sometimes sort out problems with virtual memory.
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