Click f10. Now you're at the deck gun position. The ammo option will be there at screen bottom right; (double?) click what you want.
{There might be another way...
Something like...
Click weapons officer and find the ammo sub-page --or click 'i' keyboard-- and then click the ammo type you want to use.}
As far as which ammo type is stronger...
AP might only be better when aimed at waterline against military vessels. I heard that somewhere maybe? It depends on how the sim is modeled.
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