You can save the file if you start Notepad as an Administrator first (right click on the Notepad icon in Start Menu), then locate the file and open it to make changes.
Double-clicking on the cfg or text file just opens it as a normal user. And then when saving UAC kicks in trying to prevent you from modifying files anywhere in Program Files (whatever). Though the severity will depend on how lenient you have set the UAC settings in configuration panel.
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