When you say "nhancer settings", you mean anti-aliasing? I think there are a variety of post-processing effects (if that's what they are) in SHIII that disable anti-aliasing. Whatever effect shift+page up/down adds disables it. You may have also noticed that the "wet camera lens" effect briefly disables anti-aliasing until it goes away.
All these things effect anti-aliasing, but weren't intended to. After all, the game has no built in AA of its own.
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