Hmm, i have a fairly similar system to yourself, core i5, 8gb ram and an nvidia gt540m with optimus (intel 3000 series)
I cant say ive experienced the same issue, sh3 was shown on the installed programs list and did auto select the nvidia gpu by default, im using the 285.62 drivers.
Have you tried manually adding sh3.exe and creating a profile for it? Under the game profiles you should be able to click on add and manually navigate to sh3s location.
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