If you are running windowed, there is no way to 'maximize' it. There are his res mods that will change the resolution, but those end up with their own issues I've heard. Others that have used them can give you more details.
Or if you're just trying to make it full screen as you ask, then just go into video settings and click full screen, or unclick windowed, which ever it is.
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Luck is a residue of Design.
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