I've no idea what might be causing the problems you're having, but (unless you're determined to find the cure) I can recommend finding and downloading Rapidshot v1.7. It's a standalone program that runs in the background and allows you to take screenshots as .jpg or .bmp files using whichever key combination you set it to. It can be used in any application you might be running, such as SH3 or FSX etc. I've been using it since my flightsim days on FS9 and it has worked flawlessly in all the games I've run such as Morrowind, Warcraft, Warhammer etc etc.
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